Issue 17, 2014

From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis

Abstract

The synthesis and characterisation of [Ru(H)(η5-3-phenylindenyl)(iBu-Phoban)2] 4 is reported (iBu-Phoban = 9-isobutyl-9-phosphabicyclo-[3.3.1]-nonane). 4 is obtained via alcoholysis of metathesis pre-catalyst M11, in a process that was previously thought to be limited to analogous complex [RuCl2(PPh3)2(3-phenylindenylidene)] (M10).

Graphical abstract: From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis

Supplementary files

Article information

Article type
Communication
Submitted
13 Dec 2013
Accepted
10 Jan 2014
First published
10 Jan 2014

Chem. Commun., 2014,50, 2205-2207

From ruthenium olefin metathesis catalyst to (η5-3-phenylindenyl)hydrido complex via alcoholysis

S. Manzini, D. J. Nelson, T. Lebl, A. Poater, L. Cavallo, A. M. Z. Slawin and S. P. Nolan, Chem. Commun., 2014, 50, 2205 DOI: 10.1039/C3CC49481K

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