Applying a new synthetic approach using [Co(cyclam)Cl2]Cl as educt afforded crystallization of the layered compound [Co2(cyclam)2Sn2S6]·2H2O by replacement of the axial Cl− ions in the complex by Co–S bonds to the in situ generated [Sn2S6]4− anion.
![Graphical abstract: A new synthetic approach to force bond formation between a transition metal complex and a thiostannate anion: solvothermal synthesis and crystal structure of [Co2(cyclam)2Sn2S6]·2H2O](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CE40976G&imageInfo.ImageIdentifier.Year=2013)
C. Zeisler, C. Näther and W. Bensch, CrystEngComm, 2013, 15, 8874 DOI: 10.1039/C3CE40976G
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