Issue 30, 2014

Oxidative addition of ether O-methyl bonds at a Pt(0) centre

Abstract

Pt(PCyp3)2 (Cyp = cyclopentyl) undergoes C–O oxidative addition with 2,3,5,6-tetrafluoro-4-methoxypyridine, pentafluoroanisole, 2,3,5,6-tetrafluoroanisole and 2,3,6-trifluoroanisole yielding platinum methyl derivatives. The reactions occur in preference to C–H or C–F activation.

Graphical abstract: Oxidative addition of ether O-methyl bonds at a Pt(0) centre

Supplementary files

Article information

Article type
Communication
Submitted
31 Jan 2014
Accepted
06 Feb 2014
First published
06 Feb 2014

Chem. Commun., 2014,50, 3914-3917

Author version available

Oxidative addition of ether O-methyl bonds at a Pt(0) centre

N. A. Jasim, R. N. Perutz, B. Procacci and A. C. Whitwood, Chem. Commun., 2014, 50, 3914 DOI: 10.1039/C4CC00853G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements