Issue 70, 2014

A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

Abstract

We report the first zirconium metal–organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.

Graphical abstract: A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

Supplementary files

Article information

Article type
Communication
Submitted
16 May 2014
Accepted
11 Jul 2014
First published
11 Jul 2014
This article is Open Access
Creative Commons BY license

Chem. Commun., 2014,50, 10055-10058

Author version available

A zirconium squarate metal–organic framework with modulator-dependent molecular sieving properties

B. Bueken, H. Reinsch, N. Reimer, I. Stassen, F. Vermoortele, R. Ameloot, N. Stock, C. E. A. Kirschhock and D. De Vos, Chem. Commun., 2014, 50, 10055 DOI: 10.1039/C4CC03764B

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