Issue 10, 2014

Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

Abstract

We have investigated the asymmetric allylic amination of Morita–Baylis–Hillman (MBH) carbonates with nitrogen nucleophiles in the presence of newly designed chiral DMAP catalysts. A series of α-methylene β-amino esters were obtained with good yield and selectivities.

Graphical abstract: Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

Supplementary files

Article information

Article type
Research Article
Submitted
26 Jul 2014
Accepted
09 Sep 2014
First published
10 Sep 2014

Org. Chem. Front., 2014,1, 1152-1156

Enantioselective allylic amination of MBH carbonates catalyzed by novel chiral 4-dialkylaminopyridine catalysts

G. Ma and M. P. Sibi, Org. Chem. Front., 2014, 1, 1152 DOI: 10.1039/C4QO00210E

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