Issue 37, 2016

Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile

Abstract

Incorporation of the simple, readily available, building blocks ethylene, water and acetonitrile into Au(tpy)(OCOCF3)2 (tpy = 2-(p-tolyl)pyridine) in a one-step reaction leads to high yields of a new 6-membered ring gold(III) metallacycle complex. The metallacycle has been characterized spectroscopically and crystallographically, and the mechanism of its formation has been investigated with the aid of DFT calculations.

Graphical abstract: Small-molecule activation at Au(iii): metallacycle construction from ethylene, water, and acetonitrile

Supplementary files

Article information

Article type
Paper
Submitted
27 Apr 2016
Accepted
31 May 2016
First published
10 Jun 2016
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2016,45, 14719-14724

Small-molecule activation at Au(III): metallacycle construction from ethylene, water, and acetonitrile

M. S. M. Holmsen, A. Nova, D. Balcells, E. Langseth, S. Øien-Ødegaard, E. A. Tråseth, R. H. Heyn and M. Tilset, Dalton Trans., 2016, 45, 14719 DOI: 10.1039/C6DT01648K

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