Issue 5, 2018
From the journal:

Chemical Communications

Carbodiimides as catalysts for the reduction of a cadmium hydride complex†

D. J. Webb,a   C. M. Fitchett, ORCID logo b   M. Lein ORCID logo a  and  J. R. Fulton ORCID logo *a  

* Corresponding authors

a School of Chemical and Physical Sciences, Victoria University of Wellington, PO Box 600, Wellington, New Zealand
E-mail: j.robin.fulton@vuw.ac.nz

b Department of Chemistry, University of Canterbury, P.B. 4800, Christchurch 8041, New Zealand

Abstract

A rare terminal cadmium hydride complex [(BDI)CdH] (BDI = [{N(2,6-iPr2C6H3)C(Me)}2CH]) has been synthesised from [(BDI)CdCl] and LiEt3BH. The hydride can be reduced to the cadmium(I) dimer, [(BDI)CdCd(BDI)] upon treatment with a catalytic amount of diisopropyl- or dicyclohexylcarbodiimide.

Graphical abstract: Carbodiimides as catalysts for the reduction of a cadmium hydride complex

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Article information

DOI
https://doi.org/10.1039/C7CC08393A
Article type
Communication
Submitted
01 Nov 2017
Accepted
04 Dec 2017
First published
04 Dec 2017

Chem. Commun., 2018,54, 460-462

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Carbodiimides as catalysts for the reduction of a cadmium hydride complex

D. J. Webb, C. M. Fitchett, M. Lein and J. R. Fulton, Chem. Commun., 2018, 54, 460 DOI: 10.1039/C7CC08393A

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