From ethylzinc guanidinate to [Zn10O4]-supertetrahedron

Michał K. Leszczyński; Iwona Justyniak; Karolina Zelga; Janusz Lewiński

doi:10.1039/C7DT01619K

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From ethylzinc guanidinate to [Zn₁₀O₄]-supertetrahedron†

Michał K. Leszczyński,^a Iwona Justyniak,^a Karolina Zelga^b and Janusz Lewiński

*^ab

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* Corresponding authors

^a Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
E-mail: lewin@ch.pw.edu.pl

^b Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland

Abstract

The controlled hydrolysis of an ethylzinc guanidinate complex affording an alkylzinc cluster containing a [Zn₁₀O₄]¹²⁺ supertetrahedron core stabilized by the guanidinate ligands is described. Accompanying investigations on the reactivity of this unprecedented cluster toward alcohols resulted in the formation of a mononuclear zinc alkoxide supported by the guanidinate ligands.

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Article information

DOI: https://doi.org/10.1039/C7DT01619K
Article type: Communication
Submitted: 03 May 2017
Accepted: 14 Jun 2017
First published: 14 Jun 2017
This article is Open Access

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Dalton Trans., 2017,46, 12404-12407

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From ethylzinc guanidinate to [Zn₁₀O₄]-supertetrahedron

M. K. Leszczyński, I. Justyniak, K. Zelga and J. Lewiński, Dalton Trans., 2017, 46, 12404 DOI: 10.1039/C7DT01619K

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