Issue 37, 2017

Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

Abstract

The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P4N2 is preorganized for the dicopper complex formation with the unique coordination mode in the row of P4N2 corands.

Graphical abstract: Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2017
Accepted
21 Aug 2017
First published
01 Sep 2017
This article is Open Access
Creative Commons BY license

Dalton Trans., 2017,46, 12417-12420

Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine

T. I. Wittmann, E. I. Musina, D. B. Krivolapov, I. A. Litvinov, S. A. Kondrashova, Sh. K. Latypov, A. A. Karasik and O. G. Sinyashin, Dalton Trans., 2017, 46, 12417 DOI: 10.1039/C7DT03010J

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