Issue 2, 2018

Facile synthesis of carbo- and heterocycles via Fe(iii)-catalyzed alkene hydrofunctionalization

Abstract

A facile synthesis of carbo- and heterocycles via Fe(III)-catalyzed alkene hydrofunctionalization has been developed. Various alkenes bearing a leaving group could convert to alkyl radicals through hydrogen atom transfer (HAT), and then serve as cyclization dipoles for accessing carbo- and heterocycles. The synthetic utility was further demonstrated by the synthesis of tetracyclic carbocycles from isopregol.

Graphical abstract: Facile synthesis of carbo- and heterocycles via Fe(iii)-catalyzed alkene hydrofunctionalization

Associated articles

Supplementary files

Article information

Article type
Research Article
Submitted
09 Sep 2017
Accepted
30 Sep 2017
First published
10 Oct 2017

Org. Chem. Front., 2018,5, 222-225

Facile synthesis of carbo- and heterocycles via Fe(III)-catalyzed alkene hydrofunctionalization

J. Qi, J. Zheng and S. Cui, Org. Chem. Front., 2018, 5, 222 DOI: 10.1039/C7QO00817A

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