Issue 26, 2019

Probing ultrafast dynamics during and after passing through conical intersections

Abstract

Time-resolved photoelectron spectroscopy using vacuum-UV probe pulses enables observing ultrafast dynamics during and after passing through conical intersections (CIs). The ring-puckering CI plays a prominent role following the ππ* photoexcitation of furan. More than 90% of the excited molecules safely return to the original ground state, while the remaining 10% transforms into isomers after passing through the puckering CI.

Graphical abstract: Probing ultrafast dynamics during and after passing through conical intersections

Supplementary files

Article information

Article type
Communication
Submitted
13 Jul 2018
Accepted
24 Sep 2018
First published
24 Sep 2018

Phys. Chem. Chem. Phys., 2019,21, 13902-13905

Probing ultrafast dynamics during and after passing through conical intersections

S. Adachi, T. Schatteburg, A. Humeniuk, R. Mitrić and T. Suzuki, Phys. Chem. Chem. Phys., 2019, 21, 13902 DOI: 10.1039/C8CP04426K

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