Issue 13, 2018

Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

Abstract

We have prepared 3-Cl-10-I-nido-7,8,9,11-P2C2B7H7 by the reaction of 3-Cl-nido-7,8,9,11-P2C2B7H8 with I2 in the presence of AlCl3. The product was obtained in a yield of 49% and was characterized by NMR spectroscopy and X-ray crystallography. Quantum chemical calculations have demonstrated that the crystal structure is stabilized by hydrogen, dihydrogen and pnictogen bonds.

Graphical abstract: Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

Supplementary files

Article information

Article type
Letter
Submitted
25 Jan 2018
Accepted
19 Mar 2018
First published
29 Mar 2018
This article is Open Access
Creative Commons BY-NC license

New J. Chem., 2018,42, 10481-10483

Various types of non-covalent interactions contributing towards crystal packing of halogenated diphospha-dicarbaborane with an open pentagonal belt

J. Holub, Z. Růžičková, P. Hobza, J. Fanfrlík, D. Hnyk and A. Růžička, New J. Chem., 2018, 42, 10481 DOI: 10.1039/C8NJ00450A

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