Silica cubosomes templated by a star polymer

Abstract

The organization of amphiphilic molecules into well-defined geometries and morphologies is an area of fundamental and practical importance. Herein, we report silica cubosomes synthesized by the cooperative self-assembly of the amphiphilic star polymer poly(ethylene glycol)-(polystyrene)₂. The silica cubosomes exhibit a spherical shape and a highly ordered bicontinuous diamond-surface structure. A new synthesis-field diagram was constructed based on the mass ratio of THF, HCl (2 M) and the polymer. Moreover, the mechanism of the formation of silica cubosomes has been revealed. Due to the inorganic framework, the silica cubosomes show enhanced stability and a wide scope of applications.