Issue 27, 2018
From the journal:

Chemical Science

Facile synthesis of polycyclic metallaarynes†

Wenqing Ruan,‡a   Tsz-Fai Leung,‡a   Chuan Shi,a   Ka Ho Lee,a   Herman H. Y. Sung,a   Ian D. Williams, ORCID logo *a   Zhenyang Lin ORCID logo *a  and  Guochen Jia ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong
E-mail: chwill@ust.hk, chzlin@ust.hk, chjiag@ust.hk

Abstract

Metalla-analogs of polycyclic arynes represent an interesting class of metallaaromatics with a formal M[triple bond, length as m-dash]C bond within the ring. The first examples of a bicyclic β-metallaaryne and tricyclic metallaarynes, including a metallaanthracyne and a metallaphenanthryne, were obtained in good yields by reactions of OsCl2(PPh3)3 with alkyne-functionalized phosphorus ylides.

Graphical abstract: Facile synthesis of polycyclic metallaarynes

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Article information

DOI
https://doi.org/10.1039/C8SC02086H
Article type
Edge Article
Submitted
10 May 2018
Accepted
18 Jun 2018
First published
19 Jun 2018
This article is Open Access

All publication charges for this article have been paid for by the Royal Society of Chemistry
Creative Commons BY-NC license

Chem. Sci., 2018,9, 5994-5998

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Facile synthesis of polycyclic metallaarynes

W. Ruan, T. Leung, C. Shi, K. H. Lee, H. H. Y. Sung, I. D. Williams, Z. Lin and G. Jia, Chem. Sci., 2018, 9, 5994 DOI: 10.1039/C8SC02086H

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