Issue 10, 2020
From the journal:

Chemical Communications

There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet†

Angelos B. Canaj, ORCID logo a   Sourav Dey,b   Oscar Céspedes,c   Claire Wilson, ORCID logo a   Gopalan Rajaraman ORCID logo *b  and  Mark Murrie ORCID logo *a  

* Corresponding authors

a School of Chemistry, University of Glasgow, University Avenue, Glasgow, UK
E-mail: mark.murrie@glasgow.ac.uk

b Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, Maharashtra, India
E-mail: rajaraman@chem.iitb.ac.in

c School of Physics and Astronomy, University of Leeds, Leeds LS2 9JT, UK

Abstract

A new air-stable sulfur-ligated Dy(III) single-ion magnet has been successfully isolated with Ueff = 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands significantly boost the axiality and that Te- and Se-donors have the potential to further enhance the magnetic properties.

Graphical abstract: There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(iii) single-ion magnet

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Article information

DOI
https://doi.org/10.1039/C9CC07292F
Article type
Communication
Submitted
17 Sep 2019
Accepted
23 Dec 2019
First published
26 Dec 2019
This article is Open Access
Creative Commons BY license

Chem. Commun., 2020,56, 1533-1536

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There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy(III) single-ion magnet

A. B. Canaj, S. Dey, O. Céspedes, C. Wilson, G. Rajaraman and M. Murrie, Chem. Commun., 2020, 56, 1533 DOI: 10.1039/C9CC07292F

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