A high-efficiency salamo-based copper(ii) complex double-channel fluorescent probe

Abstract

In this paper, a salamo-based copper(II) complex probe L-Cu²⁺ was synthesized, which combined with copper(II) ions to form L-Cu²⁺ for the detection of S²⁻ and had a good fluorescence chemical response. Through spectral analysis, we found that S²⁻ could be identified with high sensitivity and selectivity in the presence of various anions and could be used for the detection of S²⁻ by the naked eye. With the addition of S²⁻, the solution color changed from colorless to bright yellow. UV absorption, fluorescence and other characterization methods were carried out, and the mechanism of action was determined. In addition, we performed a visual inspection of H₂S gas, and the probe L-Cu²⁺ could detect S²⁻ in the gas molecules, revealing its potential application value in biology and medicine.