Issue 24, 1996
From the journal:

Chemical Communications

Novel intramolecular hydrogen-atom transfer in an η4-ligated cycloocta-1,5-diene η-1,2,4-triphosphole ruthenium(0) complex. Synthesis, crystal and molecular structures of [Ru(η4-C8H12){η-P3C2But2[CH(SiMe3)2]}] and [Ru(η5-C8H11){η-P3C2But2H[CH(SiMe3)2]}]

Peter B. Hitchcock,   John F. Nixon  and  Nurgün Sakarya  

Abstract

The first known ruthenium(0) complex of a 1,2,4-triphosphole is reported which undergoes a novel hydrogen migration reaction from the η4-cycloocta-1,5-diene coligand on heating.

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Article information

DOI
https://doi.org/10.1039/CC9960002751
Article type
Paper

Chem. Commun., 1996, 2751-2752

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Novel intramolecular hydrogen-atom transfer in an η4-ligated cycloocta-1,5-diene η-1,2,4-triphosphole ruthenium(0) complex. Synthesis, crystal and molecular structures of [Ru(η4-C8H12){η-P3C2But2[CH(SiMe3)2]}] and [Ru(η5-C8H11){η-P3C2But2H[CH(SiMe3)2]}]

P. B. Hitchcock, J. F. Nixon and N. Sakarya, Chem. Commun., 1996, 2751 DOI: 10.1039/CC9960002751

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