Issue 27, 2020

Pd-Catalyzed intermolecular C–H bond arylation reactions: effect of bulkiness of carboxylate ligands

Abstract

A bulky carboxylic acid bearing one 1-adamantylmethyl and two methyl substituents at the α-position is demonstrated to work as an efficient carboxylate ligand source in Pd-catalyzed intermolecular C(sp2)–H bond arylation reactions. The reactions proceeded smoothly under mild conditions, taking advantage of the steric bulk of the carboxylate ligands.

Graphical abstract: Pd-Catalyzed intermolecular C–H bond arylation reactions: effect of bulkiness of carboxylate ligands

Supplementary files

Article information

Article type
Communication
Submitted
12 Feb 2020
Accepted
04 Mar 2020
First published
05 Mar 2020

Chem. Commun., 2020,56, 3843-3846

Pd-Catalyzed intermolecular C–H bond arylation reactions: effect of bulkiness of carboxylate ligands

Y. Tanji, R. Hamaguchi, Y. Tsuji and T. Fujihara, Chem. Commun., 2020, 56, 3843 DOI: 10.1039/D0CC01129K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements