Issue 53, 2020

Constructing multi-cluster copper(i) halides using conformationally flexible ligands

Abstract

Three unprecedented multi-cluster copper(I) halides (MCCHs) have been assembled using conformationally flexible ligands. Further explorations demonstrate that the conformational compliance of the ligands may be the key to trap and stabilize the various copper(I)-halide clusters in one system, which opens a new way for the construction of multi-Cu(I)-cluster complexes. Moreover, the MCCHs show distinctive temperature-dependent photoluminescence.

Graphical abstract: Constructing multi-cluster copper(i) halides using conformationally flexible ligands

Supplementary files

Article information

Article type
Communication
Submitted
06 Apr 2020
Accepted
23 May 2020
First published
26 May 2020

Chem. Commun., 2020,56, 7233-7236

Constructing multi-cluster copper(I) halides using conformationally flexible ligands

M. Yu, C. Liu, S. Li, Y. Zhao, J. Lv, Z. Zhuo, F. Jiang, L. Chen, Y. Yu and M. Hong, Chem. Commun., 2020, 56, 7233 DOI: 10.1039/D0CC02472D

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