Issue 100, 2020

Unravelling the local structure of catalytic Fe-oxo clusters stabilized on the MOF-808 metal organic-framework

Abstract

Stabilizing catalytic iron-oxo-clusters within nanoporous metal–organic frameworks (MOFs) is a powerful strategy to prepare new active materials for the degradation of toxic chemicals, such as bisphenol A. Herein, we combine pair distribution function analysis of total X-ray scattering data and X-ray absorption spectroscopy, with computational modelling to understand the local structural nature of added redox-active iron-oxo clusters bridging neighbouring zirconia-nodes within MOF-808.

Graphical abstract: Unravelling the local structure of catalytic Fe-oxo clusters stabilized on the MOF-808 metal organic-framework

Supplementary files

Article information

Article type
Communication
Submitted
10 Sep 2020
Accepted
20 Nov 2020
First published
23 Nov 2020

Chem. Commun., 2020,56, 15615-15618

Unravelling the local structure of catalytic Fe-oxo clusters stabilized on the MOF-808 metal organic-framework

C. Castillo-Blas, I. Romero-Muñiz, A. Mavrandonakis, L. Simonelli and A. E. Platero-Prats, Chem. Commun., 2020, 56, 15615 DOI: 10.1039/D0CC06134D

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