Highly efficient In2S3/WO3 photocatalysts: Z-scheme photocatalytic mechanism for enhanced photocatalytic water pollutant degradation under visible light irradiation

Abstract

A Z-scheme system In₂S₃/WO₃ heterojunction was fabricated via a mild hydrothermal method and further applied for photocatalytic degradation of tetracycline (TCH) and Rhodamine B (Rh B) under visible light irradiation. The morphological structure, chemical composition and optical properties were studied by XRD, SEM, HRTEM and UV-visible absorption spectra. The results revealed that In₂S₃/WO₃ hierarchical structures were successfully constructed, and the prepared In₂S₃/WO₃ photocatalysts exhibited enhanced visible-light absorption compared to pure WO₃ nanorods, which are essential to improve the photocatalytic performance. The degradation rate of TCH using the In₂S₃(40 wt%)/WO₃ heterostructure (WI40) photocatalyst was about 212 times and 22 times as high as that for pure WO₃ and pure In₂S₃, respectively. The degradation rate of Rh B with the WI40 photocatalyst was about 56 times the efficiency of pure WO₃ and 7.6 times that of pure In₂S₃. The results of the surface photovoltage (SPV), transient photovoltage (TPV) and reactive oxidation species (ROS) scavenger experiments indicated that the Z-scheme system of In₂S₃/WO₃ is favorable for photoexcited charge transfer at the contact interface of In₂S₃ and WO₃, which benefits the charge separation efficiency and depresses the recombination of photoexcited charge, resulting in favorable photocatalytic pollutant degradation efficiency under visible light irradiation.