Issue 33, 2021

Green-light induced cycloadditions

Abstract

We introduce a red-shifted tetrazole that is able to undergo efficient nitrile imine-mediated tetrazoleene cycloaddition (NITEC) under blue and green light irradiation. We provide a detailed wavelength-dependent reactivity map, and employ a number of LEDs for high-conversion small molecule and polymer end-group modification.

Graphical abstract: Green-light induced cycloadditions

Supplementary files

Article information

Article type
Communication
Submitted
20 Jan 2021
Accepted
17 Mar 2021
First published
17 Mar 2021
This article is Open Access
Creative Commons BY license

Chem. Commun., 2021,57, 3991-3994

Green-light induced cycloadditions

P. W. Kamm, J. P. Blinco, A. Unterreiner and C. Barner-Kowollik, Chem. Commun., 2021, 57, 3991 DOI: 10.1039/D1CC00340B

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