Higher MLCT lifetime of carbene iron(ii) complexes by chelate ring expansion

Abstract

Combining strong σ-donating N-heterocyclic carbene ligands and π-accepting pyridine ligands with a high octahedricity in rigid iron(II) complexes increases the ³MLCT lifetime from 0.15 ps in the prototypical [Fe(tpy)₂]²⁺ complex to 9.2 ps in [Fe(dpmi)₂]²⁺1²⁺. The tripodal CNN ligand dpmi (di(pyridine-2-yl)(3-methylimidazol-2-yl)methane) forms six-membered chelate rings with the iron(II) centre leading to close to 90° bite angles and enhanced iron-ligand orbital overlap.