From organotin hydrides to heteronuclear main group metal compounds: isolation of the first neutral bismuth/tin clusters

Abstract

From conversions of Ar₂SnH₂ (Ar = Tripp, Dipp; Tripp = 2,4,6-Triisopropylphenyl, Dipp = 2,6-Diisopropylphenyl), and a bismuth(III) amide, Bi[N(SiMe₃)₂]₃, we isolated the first representatives of mixed, uncharged Bi/Sn clusters, Bi₈Sn₃Ar₆. Along with unprecedented bicyclo[2.2.0]hexanes, (HAr₂Sn)₂Sn₂Bi₄, these have been characterized by single crystal X-Ray diffraction, heteronuclear NMR, vibrational and UV-Vis spectroscopy. Quantum-chemical calculations were carried out in order to understand bonding within the isolated polyhedral compounds.