Issue 15, 1972
From the journal:

Journal of the Chemical Society, Dalton Transactions

Nitrato-complexes of iridium. Part I. Ir3O(NO3)10

B. Harrison  and  N. Logan  

Abstract

The new oxide nitrate of iridium(IV), Ir3O(NO3)10, is prepared from dinitrogen pentoxide and iridium tribromide. The i.r. spectrum suggests its formulation as [Ir3O(NO3)9]+NO3– its electronic spectra, X-ray powder pattern, room temperature magnetic moment, and chemical properties are discussed. A trinuclear structure involving pairs of nitrate bridges between octahedrally co-ordinated iridium atoms is suggested for the cation [Ir3O(NO3)9]+. The reaction between iridium tribromide and 100% nitric acid has also been studied.

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Article information

DOI
https://doi.org/10.1039/DT9720001587
Article type
Paper

J. Chem. Soc., Dalton Trans., 1972, 1587-1589

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Nitrato-complexes of iridium. Part I. Ir3O(NO3)10

B. Harrison and N. Logan, J. Chem. Soc., Dalton Trans., 1972, 1587 DOI: 10.1039/DT9720001587

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