Pyrolysis of [Co(CO)4(SiH3)], [Fe(CO)4(SiH3)2], and [Mn(CO)5(SiH3)] at 773 K in a flow system affords the transition-metal silicldes CoSi, β-FeSi2 and MnSi–Mn5Si3 respectively. Static pyrolysis of [Mn(CO)5(SiH3)] gives only amorphous solid products which contain, in addition to metal and silicon, appreciable quantities of carbon, hydrogen, and oxygen.
B. J. Aylett and H. M. Colquhoun, J. Chem. Soc., Dalton Trans., 1977, 2058 DOI: 10.1039/DT9770002058
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