An analogue of the salts of Millon's base, (Hg2P)2HgBr4, was prepared by a solid-state synthesis; its crystal structure is based on a three-dimensional net, the tunnels of which are filled by columns of apex-shared, disordered HgBr5 trigonal bipyramids.
A. V. Shevelkov, M. Yu. Mustyakimov, E. V. Dikarev and B. A. Popovkin, J. Chem. Soc., Dalton Trans., 1996, 147 DOI: 10.1039/DT9960000147
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