Preparation, properties, and isomerisation of aquofluorobis(ethylenediamine)cobalt(III) cations
Abstract
The preparation and characterisation of aquofluorobis(ethylenediamine)cobalt(III) cations are described. Spectral measurements are used to establish their geometrical configurations. The rates of isomeric interconversion of these cations in aqueous solutions at various temperatures, together with the position of equilibrium, are reported.