Issue 0, 1966
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


The oxidation of some ruthenium(II) complexes of o-phenanthroline and bipyridyl by thallic ion in perchloric acid

J. D. Miller  and  R. H. Prince  

Abstract

The order of reaction, rate constants, and activation energies, for the oxidation of eleven ruthenium(II) complexes, in 4·75M-perchloric acid medium, have been studied. The effects of solvent, light, and added compounds on the rate of reaction are also reported, and a reaction mechanism is postulated, which accords with the equations Ru(o-phen)32++ Tl3+⇌ Ru(o-phen)33++ Tl2+, Ru(o-phen)32++ Tl2+→ Ru(o-phen)33++ Tl+(fast)

The visible and ultraviolet spectra of the complexes and some of their oxidation–reduction potentials are also reported.

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Article information

DOI
https://doi.org/10.1039/J19660001048
Article type
Paper

J. Chem. Soc. A, 1966, 1048-1052

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The oxidation of some ruthenium(II) complexes of o-phenanthroline and bipyridyl by thallic ion in perchloric acid

J. D. Miller and R. H. Prince, J. Chem. Soc. A, 1966, 1048 DOI: 10.1039/J19660001048

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