Issue 0, 1979

Unsaturated carbohydrates. Part 21. A carbocyclic ring closure of a hex-5-enopyranoside derivative

Abstract

Heating of the unsaturated glycoside triester (1) in refluxing aqueous acetone with mercury(II) chloride gave the cyclohexenone derivative (4) in high yield in a reaction which represents a new means of obtaining functionalised carbocyclic compounds from carbohydrates. From compound (4), the substituted cyclohexenone (5) and thence the phenol (6) were prepared.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1979, 1455-1458

Unsaturated carbohydrates. Part 21. A carbocyclic ring closure of a hex-5-enopyranoside derivative

R. J. Ferrier, J. Chem. Soc., Perkin Trans. 1, 1979, 1455 DOI: 10.1039/P19790001455

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