Issue 1, 2011

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

Abstract

A combination of IPrAuNTf2 as catalyst in the presence of Selectfluor has been successfully used for the high yielding synthesis of α-fluoroenones via 1,3-acyloxy rearrangement of propargyl acetates followed by Csp2–F bond formation, likely involving a redox Au(I)/Au(III) catalytic cycle.

Graphical abstract: Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

Supplementary files

Article information

Article type
Communication
Submitted
10 Feb 2010
Accepted
28 May 2010
First published
29 Jun 2010

Chem. Commun., 2011,47, 248-249

Domino gold-catalyzed rearrangement and fluorination of propargyl acetates

T. de Haro and C. Nevado, Chem. Commun., 2011, 47, 248 DOI: 10.1039/C002679D

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