Issue 11, 2011
From the journal:

Chemical Communications

Co and Mn polysiloxanes as unique initiator–catalyst-systems for the selective liquid phase oxidation of o-xylene†

Tobias Förster,a   Stephan A. Schunk,b   Andreas Jentysa  and  Johannes A. Lercher*b  

* Corresponding authors

a Department of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstraße 4, 85747 Garching, Germany
E-mail: johannes.lercher@ch.tum.de
Fax: +49 89 289 13544
Tel: +49 89 289 13541

b hte Aktiengesellschaft, Kurpfalzring 104, 69123 Heidelberg, Germany
E-mail: stephan.schunk@hte-company.de
Fax: +49 6221 7497 0
Tel: +49 6221 7497 111

Abstract

Co and Mn polysiloxanes are unique catalyst/initiator systems for the liquid phase oxidation of o-xylene showing higher activity than Co naphthenates, which is related to the weak interaction of the polar products with the hydrophobic surface as well as the absence of hydroxyl groups and surrounding oxygenates limiting radical quenching.

Graphical abstract: Co and Mn polysiloxanes as unique initiator–catalyst-systems for the selective liquid phase oxidation of o-xylene

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Article information

DOI
https://doi.org/10.1039/C0CC05050D
Article type
Communication
Submitted
19 Nov 2010
Accepted
12 Jan 2011
First published
28 Jan 2011

Chem. Commun., 2011,47, 3254-3256

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Co and Mn polysiloxanes as unique initiator–catalyst-systems for the selective liquid phase oxidation of o-xylene

T. Förster, S. A. Schunk, A. Jentys and J. A. Lercher, Chem. Commun., 2011, 47, 3254 DOI: 10.1039/C0CC05050D

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