Issue 20, 2011
From the journal:

Dalton Transactions

Synthesis, characteristics and photoluminescent properties of novel Ir–Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand†

Ping Lian,ab   Huibo Wei,a   Chen Zheng,a   Yifan Nie,a   Jiang Bian,a   Zuqiang Bian*a  and  Chunhui Huanga  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China
E-mail: bianzq@pku.edu.cn
Fax: +86 10-6275-7156
Tel: +86 10-6275-3544

b College of Chemistry and Life Science, Gannan Normal University, Ganzhou, Jiangxi, China

Abstract

Two novel iridium(III) complexes, [Ir(dfppy)2(pmc)] and [Ir(ppy)2(pmc)] (dfppy = 2-(4′,6′-difluoro-phenyl)pyridine, ppy = 1-phenyl-pyridine), were designed and synthesized using 2-carboxyl-pyrimidine (Hpmc) as an ancillary ligand. Single crystals were obtained and characterized by single crystal X-ray diffraction. The tetrametallic complexes {[(C⁁N)2Ir(μ-pmc)]3EuCl3} (C⁁N = dfppy, ppy) were synthesized using the iridium(III) complexes as “ligands”. Photophysical and theoretical studies indicate that [Ir(dfppy)2(pmc)] is more suitable for sensitizing the emission of Eu(III) ions than [Ir(ppy)2(pmc)].

Graphical abstract: Synthesis, characteristics and photoluminescent properties of novel Ir–Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand

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Article information

DOI
https://doi.org/10.1039/C0DT01592J
Article type
Paper
Submitted
16 Nov 2010
Accepted
22 Feb 2011
First published
16 Mar 2011

Dalton Trans., 2011,40, 5476-5482

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Synthesis, characteristics and photoluminescent properties of novel Ir–Eu heteronuclear complexes containing 2-carboxyl-pyrimidine as a bridging ligand

P. Lian, H. Wei, C. Zheng, Y. Nie, J. Bian, Z. Bian and C. Huang, Dalton Trans., 2011, 40, 5476 DOI: 10.1039/C0DT01592J

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