Issue 17, 2011
From the journal:

Chemical Communications

Metal–ligand bifunctional activation and transfer of N–H bonds†

Kilian Muñiz,*ab   Anton Lishchynskyi,a   Jan Streuff,c   Martin Nieger,d   Eduardo C. Escudero-Adána  and  Marta Martínez Belmontea  

* Corresponding authors

a Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans, 16, E-43007 Tarragona, Spain
E-mail: kmuniz@iciq.es

b Catalan Institution for Research and Advanced Studies (ICREA), Pg. Lluís Companys 23, 08010 Barcelona, Spain

c Albert-Ludwigs-Universität Freiburg, Albertstr. 21, 79104 Freiburg, Germany

d Department of Chemistry, P.O. Box 55, FI-00014 University of Helsinki, Finland

Abstract

The concept of metal–ligand bifunctionality can be employed for an efficient activation of N–H bonds by well-defined ruthenium amido complexes. An enantioselective catalytic aza-Michael reaction was developed on the basis of this process, which gives rise to indoline β-amino acids.

Graphical abstract: Metal–ligand bifunctional activation and transfer of N–H bonds

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Article information

DOI
https://doi.org/10.1039/C1CC10999E
Article type
Communication
Submitted
20 Feb 2011
Accepted
10 Mar 2011
First published
24 Mar 2011

Chem. Commun., 2011,47, 4911-4913

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Metal–ligand bifunctional activation and transfer of N–H bonds

K. Muñiz, A. Lishchynskyi, J. Streuff, M. Nieger, E. C. Escudero-Adán and M. M. Belmonte, Chem. Commun., 2011, 47, 4911 DOI: 10.1039/C1CC10999E

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