Zinc–zinc bonded decamethyldizincocene Zn2(η5-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction

Anja Lühl; Hari Pada Nayek; Siegfried Blechert; Peter W. Roesky

doi:10.1039/C1CC12461G

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Zinc–zinc bonded decamethyldizincocene Zn₂(η⁵-C₅Me₅)₂ as catalyst for the inter- and intramolecular hydroamination reaction†

Anja Lühl,^a Hari Pada Nayek,^a Siegfried Blechert*^b and Peter W. Roesky*^a

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* Corresponding authors

^a Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
E-mail: roesky@kit.edu
Fax: (+49) 721-608-44854
Tel: (+49) 721-608-46117

^b Technische Universität Berlin, Institut für Chemie, Straße des 17. Juni 135, 10623 Berlin, Germany
E-mail: blechert@chem.tu-berlin.de
Fax: +49 (0)30-31 42 36 19
Tel: +49 (0)30-31 42 23 55

Abstract

The Zn–Zn bonded compound [(η⁵-Cp*)₂Zn₂] was investigated as catalyst for the inter- and intramolecular hydroamination reaction. High reaction rates under mild conditions were observed. This is the first application of a Zn–Zn bonded compound as catalyst.

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Article information

DOI: https://doi.org/10.1039/C1CC12461G
Article type: Communication
Submitted: 27 Apr 2011
Accepted: 05 Jun 2011
First published: 24 Jun 2011

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Chem. Commun., 2011,47, 8280-8282

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Zinc–zinc bonded decamethyldizincocene Zn₂(η⁵-C₅Me₅)₂ as catalyst for the inter- and intramolecular hydroamination reaction

A. Lühl, H. Pada Nayek, S. Blechert and P. W. Roesky, Chem. Commun., 2011, 47, 8280 DOI: 10.1039/C1CC12461G

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