Issue 35, 2011

Peripherally cyclometalated iridium complexes of dipyridylporphyrin

Abstract

Two types of novel iridium pincer complexes bearing a porphyrin backbone were synthesized and characterized from dipyridylporphyrin. One of the complexes has a Lewis acidic site on the iridium center in the mer-coordination mode. The other complex takes the fac-coordination, which is rarely observed in benzene-based pincer complexes.

Graphical abstract: Peripherally cyclometalated iridium complexes of dipyridylporphyrin

Supplementary files

Article information

Article type
Communication
Submitted
14 Feb 2011
Accepted
11 Apr 2011
First published
03 May 2011

Dalton Trans., 2011,40, 8773-8775

Peripherally cyclometalated iridium complexes of dipyridylporphyrin

K. Yoshida, T. Nakashima, S. Yamaguchi, A. Osuka and H. Shinokubo, Dalton Trans., 2011, 40, 8773 DOI: 10.1039/C1DT10246J

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