Issue 11, 2011
From the journal:

Green Chemistry

Investigating the formation of dialkyl carbonates using high speed ball milling

Daniel C. Waddell,a   Indre Thiel,a   Ashley Bunger,a   Dominique Nkata,a   Ashley Maloney,a   Tammara Clark,a   Brandon Smitha  and  James Mack*a  

* Corresponding authors

a Department of Chemistry, University of Cincinnati, 301 Clifton Court, Cincinnati, OH, USA
E-mail: james.mack@uc.edu

Abstract

We investigated the synthesis of dialkyl carbonates under solvent-free high speed ball milling conditions. We converted various metal carbonates with the assistance of metal complexing reagents into a variety of dialkyl carbonates. We also observed the increased reactivity of urea under similar reaction conditions.

Graphical abstract: Investigating the formation of dialkyl carbonates using high speed ball milling

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Article information

DOI
https://doi.org/10.1039/C1GC15594F
Article type
Paper
Submitted
24 May 2011
Accepted
01 Sep 2011
First published
30 Sep 2011

Green Chem., 2011,13, 3156-3161

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Investigating the formation of dialkyl carbonates using high speed ball milling

D. C. Waddell, I. Thiel, A. Bunger, D. Nkata, A. Maloney, T. Clark, B. Smith and J. Mack, Green Chem., 2011, 13, 3156 DOI: 10.1039/C1GC15594F

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