Issue 14, 2011

A supramolecular approach to zwitterionic alkaline metal silanides and formation of heterobimetallic silanides

Abstract

Incorporating pendant polydonor groups is key to the synthesis and isolation of a series of novel and truly zwitterionic alkaline metal silanides of formula {Si[SiMe2O(CH2)nOMe]3}M (n = 2, 3; M = Li, Na, K) that can easily be converted into heterobimetallic silanides.

Graphical abstract: A supramolecular approach to zwitterionic alkaline metal silanides and formation of heterobimetallic silanides

Supplementary files

Article information

Article type
Communication
Submitted
07 Jan 2011
Accepted
15 Feb 2011
First published
07 Mar 2011

Chem. Commun., 2011,47, 4117-4119

A supramolecular approach to zwitterionic alkaline metal silanides and formation of heterobimetallic silanides

H. Li, L. J. Hope-Weeks and C. Krempner, Chem. Commun., 2011, 47, 4117 DOI: 10.1039/C1CC10148J

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