Issue 2, 2013
From the journal:

Catalysis Science & Technology

Highly efficient and expeditious PdO/SBA-15 catalysts for allylic oxidation of cyclohexene to cyclohexenone

Saidulu Ganji,a   Padma Bukya,a   Venkateswarlu Vakati,a   Kamaraju Seetha Rama Raoa  and  David Raju Burri*a  

* Corresponding authors

a Catalysis Laboratory, Indian Institute of Chemical Technology, Hyderabad-500607, India
E-mail: david@iict.res.in
Fax: +91-40-27160921
Tel: +91-40-27191712

Abstract

A series of four PdO/SBA-15 catalysts with 1, 2, 4, 5% (by weight) loading of PdO have been prepared by a conventional impregnation method and are characterized by N2-adsorption, low-angle and wide-angle XRD, XPS and TEM techniques. The catalysts exhibited very high conversion of cyclohexene and high selectivity of cyclohexenone with 70% t-BuOOH in CH3CN. The structural and textural characteristics of catalysts play a crucial role in high conversion and selectivity.

Graphical abstract: Highly efficient and expeditious PdO/SBA-15 catalysts for allylic oxidation of cyclohexene to cyclohexenone

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Article information

DOI
https://doi.org/10.1039/C2CY20627G
Article type
Communication
Submitted
07 Sep 2012
Accepted
22 Nov 2012
First published
23 Nov 2012

Catal. Sci. Technol., 2013,3, 409-414

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Highly efficient and expeditious PdO/SBA-15 catalysts for allylic oxidation of cyclohexene to cyclohexenone

S. Ganji, P. Bukya, V. Vakati, K. S. R. Rao and D. R. Burri, Catal. Sci. Technol., 2013, 3, 409 DOI: 10.1039/C2CY20627G

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