Issue 4, 2012
From the journal:

Green Chemistry

An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation†

Simon Doherty,*a   Julian G. Knight,*a   Jack R. Ellison,a   David Weekes,a   Ross W. Harrington,a   Christopher Hardacre*b  and  Haresh Manyarb  

* Corresponding authors

a School of Chemistry, Bedson Building, Newcastle University, Newcastle upon Tyne, England
E-mail: simon.doherty@ncl.ac.uk
Fax: +44 0191 222 6929
Tel: +44 0191 222 6537

b School of Chemistry and Chemical Engineering, David Keir Building, Queen's University, Stranmillis Road, Belfast, Northern Ireland
E-mail: c.hardacre@qub.ac.uk
Fax: +44 02890976524
Tel: +44 02890976524

Abstract

A linear cation-decorated polymeric support with tuneable surface properties and microstructure has been prepared by ring-opening metathesis polymerisation (ROMP) of a pyrrolidinium-functionalised norbornene-based monomer with cyclooctene. The derived peroxophosphotungstate-based polymer-immobilised ionic liquid phase (PIILP) catalyst is an efficient and recyclable system for the epoxidation of allylic alcohols and alkenes, with only a minor reduction in performance on successive cycles.

Graphical abstract: An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation

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Article information

DOI
https://doi.org/10.1039/C2GC16679H
Article type
Communication
Submitted
28 Dec 2011
Accepted
16 Feb 2012
First published
06 Mar 2012

Green Chem., 2012,14, 925-929

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An efficient recyclable peroxometalate-based polymer-immobilised ionic liquid phase (PIILP) catalyst for hydrogen peroxide-mediated oxidation

S. Doherty, J. G. Knight, J. R. Ellison, D. Weekes, R. W. Harrington, C. Hardacre and H. Manyar, Green Chem., 2012, 14, 925 DOI: 10.1039/C2GC16679H

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