Issue 25, 2012
From the journal:

Organic & Biomolecular Chemistry

Precipitation-driven self-sorting of imines†

Rio Carlo Lirag,a   Karolina Osowska‡a  and  Ognjen Š. Miljanić*a  

* Corresponding authors

a University of Houston, Department of Chemistry, 136 Fleming Building, Houston, TX 77204-5003, USA
E-mail: miljanic@uh.edu
Fax: +1 (713) 743-2709
Tel: +1 (832) 842-8827

Abstract

Judicious choice of precipitation conditions can lead to self-sorting of equilibrating mixtures of aromatic aldehydes and substituted anilines into a handful of imine products. The selectivity of this process is caused by the solubility differences among possible imines in the EtOH–H2O solvent mixtures used in precipitation.

Graphical abstract: Precipitation-driven self-sorting of imines

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Article information

DOI
https://doi.org/10.1039/C2OB25736J
Article type
Communication
Submitted
16 Apr 2012
Accepted
21 May 2012
First published
21 May 2012

Org. Biomol. Chem., 2012,10, 4847-4850

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Precipitation-driven self-sorting of imines

R. C. Lirag, K. Osowska and O. Š. Miljanić, Org. Biomol. Chem., 2012, 10, 4847 DOI: 10.1039/C2OB25736J

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