Issue 21, 1974

Monomeric, volatile bivalent amides of group IVB elements, M(NR12)2 and M(NR1R2)2(M[double bond, length half m-dash]Ge, Sn, or Pb; R1[double bond, length half m-dash]Me3Si, R2[double bond, length half m-dash]Me3C)

Abstract

The reactions of SnCl2, PbCl2, or GeCl2, dioxan with LiNR12, OEt2 or LiNR1R2, OEt2 in Et2O at 0° yield the stable, monomeric, diamagnetic, coloured, volatile, hydrocarbon-soluble title compounds which are highly reactive.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 895-896

Monomeric, volatile bivalent amides of group IVB elements, M(NR12)2 and M(NR1R2)2(M[double bond, length half m-dash]Ge, Sn, or Pb; R1[double bond, length half m-dash]Me3Si, R2[double bond, length half m-dash]Me3C)

D. H. Harris and M. F. Lappert, J. Chem. Soc., Chem. Commun., 1974, 895 DOI: 10.1039/C39740000895

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