Issue 7, 2014

Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor

Abstract

Supramolecular CH⋯π interactions cause a ruffling of the otherwise coplanar ribbon-like arrays of radicals in the structure of the oxobenzene-bridged bisdithiazolyl 1a. The material displays a conductivity σ(300 K) = 6 × 10−3 S cm−1 (Eact = 0.16 eV) and orders antiferromagnetically below 4 K. At applied fields above 1 kOe the material displays metamagnetic behavior.

Graphical abstract: Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor

Supplementary files

Article information

Article type
Communication
Submitted
02 Sep 2013
Accepted
25 Sep 2013
First published
14 Oct 2013

Chem. Commun., 2014,50, 785-787

Supramolecular architecture, crystal structure and transport properties of the prototypal oxobenzene-bridged bisdithiazolyl radical conductor

J. W. L. Wong, A. Mailman, S. M. Winter, C. M. Robertson, R. J. Holmberg, M. Murugesu, P. A. Dube and R. T. Oakley, Chem. Commun., 2014, 50, 785 DOI: 10.1039/C3CC46686H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements