Issue 14, 2014
From the journal:

Chemical Communications

One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst†

Paula Rubio-Marqués,a   Juan Carlos Hernández-Garrido,b   Antonio Leyva-Pérez*a  and  Avelino Corma*a  

* Corresponding authors

a Instituto de Tecnología Química, Universidad Politécnica de Valencia-Consejo Superior de Investigaciones Científicas (UPV-CSIC.), Avda. De los Naranjos S/N, Valencia, Spain
E-mail: anleyva@itq.upv.es, acorma@itq.upv.es
Fax: +34 96 387 7809
Tel: +34 96 387 7800

b Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Campus Río San Pedro S/N, Puerto Real-Cádiz, Spain

Abstract

Cyclohexanone oxime is formed from nitrobenzene with 97% yield in a one-pot reaction catalysed by palladium and gold nanoparticles on carbon. The reaction is carried out under hydrogen at 60 °C and the overall transformation involves a multi-step catalysed mechanism from which intermediates and catalytically active species have been identified.

Graphical abstract: One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst

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Article information

DOI
https://doi.org/10.1039/C3CC47693F
Article type
Communication
Submitted
07 Oct 2013
Accepted
04 Nov 2013
First published
05 Nov 2013

Chem. Commun., 2014,50, 1645-1647

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One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst

P. Rubio-Marqués, J. C. Hernández-Garrido, A. Leyva-Pérez and A. Corma, Chem. Commun., 2014, 50, 1645 DOI: 10.1039/C3CC47693F

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