Issue 22, 2013
From the journal:

CrystEngComm

Toward chiral conductors: combining halogen bonding ability and chirality within a single tetrathiafulvalene molecule†

Julien Lieffrig,a   Ronan Le Pennec,a   Olivier Jeannin,a   Pascale Auban-Senzierb  and  Marc Fourmigué*a  

* Corresponding authors

a Institut des Sciences Chimiques de Rennes, Université Rennes 1, UMR CNRS 6226, Campus de Beaulieu, 35042 Rennes, France
E-mail: marc.fourmigue@univ-rennes1.fr

b Laboratoire de Physique des Solides, Université Paris-Sud, UMR CNRS 8502, Bât. 510, 91405 Orsay, France

Abstract

Chirality and halogen bonding ability are combined in a single tetrathiafulvalene molecule (1) with iodo and dimethyl(propylenedithio) substituents, with I⋯I interactions developing along a 21 screw axis. The chiral mixed-valence conducting salt (1)2Cl exhibits a strongly 1D electronic structure.

Graphical abstract: Toward chiral conductors: combining halogen bonding ability and chirality within a single tetrathiafulvalene molecule

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Article information

DOI
https://doi.org/10.1039/C3CE40393A
Article type
Communication
Submitted
04 Mar 2013
Accepted
27 Mar 2013
First published
28 Mar 2013

CrystEngComm, 2013,15, 4408-4412

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Toward chiral conductors: combining halogen bonding ability and chirality within a single tetrathiafulvalene molecule

J. Lieffrig, R. L. Pennec, O. Jeannin, P. Auban-Senzier and M. Fourmigué, CrystEngComm, 2013, 15, 4408 DOI: 10.1039/C3CE40393A

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