Issue 15, 2013
From the journal:

Dalton Transactions

Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide†

Brian G. Alberding,a   Samantha E. Brown-Xu,a   Malcolm H. Chisholm,*a   Arthur J. Epstein,a   Terry L. Gustafson,a   Sharlene A. Lewisa  and  Yong Mina  

* Corresponding authors

a The Ohio State University, 100 West 18th Avenue, Columbus, OH, USA
E-mail: chisholm@chemistry.ohio-state.edu
Fax: +1 614-292-0368
Tel: +1 614-688-3625

Abstract

Evidence, based on femtosecond transient absorption and time resolved infrared spectroscopy, is presented for photoinduced charge transfer from the Mo2δ orbital of the quadruply bonded molecule trans-Mo2(TiPB)2(BTh)2, where TiPB = 2,4,6-triisopropyl benzoate and BTh = 2,2′-bithienylcarboxylate, to di-n-octyl perylene diimide and di-n-hexylheptyl perylene diimide in thin films and solutions of the mixtures. The films show a long-lived charge separated state while slow back electron transfer, τBET ∼ 500 ps, occurs in solution.

Graphical abstract: Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide

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Article information

DOI
https://doi.org/10.1039/C3DT32750G
Article type
Paper
Submitted
18 Nov 2012
Accepted
30 Jan 2013
First published
04 Feb 2013

Dalton Trans., 2013,42, 5275-5280

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Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide

B. G. Alberding, S. E. Brown-Xu, M. H. Chisholm, A. J. Epstein, T. L. Gustafson, S. A. Lewis and Y. Min, Dalton Trans., 2013, 42, 5275 DOI: 10.1039/C3DT32750G

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