Issue 22, 2013
From the journal:

Dalton Transactions

Palladium complexes with stabilized germylene and stannylene ligands†

Marina M. Kireenko,a   Kirill V. Zaitsev,*a   Yuri F. Oprunenko,a   Andrei V. Churakov,b   Viktor A. Tafeenko,a   Sergey S. Karlov*a  and  Galina S. Zaitsevaa  

* Corresponding authors

a B-234 Leninskie Gory, Chemistry Department, Moscow State University, 119991 Moscow, Russia
E-mail: zaitsev@org.chem.msu.ru, sergej@org.chem.msu.ru
Fax: +7-495-932-8846
Tel: +7-495-9393887

b Leninskii pr., 31, Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia

Abstract

The syntheses of novel Pd complexes with germylene and stannylene ligands are reported. [MeN(CH2CH2NC6F5)2Sn]4Pd (2) and [MeN(CH2CPh2O)(CH2CH2O)Ge]4Pd (8) were obtained by different methods including ligand substitution in (Ph3P)4Pd or by the reaction of the free corresponding germylene or stannylene with (Ph3P)2PdCl2 or Pd(OAc)2. Crystal structures of complexes 2, 8 were determined by single crystal X-ray diffraction analysis. The catalytic activity of complexes 2, 8 was examined in the Suzuki–Miyaura and Heck cross-coupling.

Graphical abstract: Palladium complexes with stabilized germylene and stannylene ligands

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Article information

DOI
https://doi.org/10.1039/C3DT32867H
Article type
Paper
Submitted
29 Nov 2012
Accepted
22 Jan 2013
First published
23 Jan 2013

Dalton Trans., 2013,42, 7901-7912

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Palladium complexes with stabilized germylene and stannylene ligands

M. M. Kireenko, K. V. Zaitsev, Y. F. Oprunenko, A. V. Churakov, V. A. Tafeenko, S. S. Karlov and G. S. Zaitseva, Dalton Trans., 2013, 42, 7901 DOI: 10.1039/C3DT32867H

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