Issue 39, 2013

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound

Abstract

Tris(2-pyridonyl)methanes may be synthesized via the reactions of the respective 2-pyridone with CHX3 (X = Cl, Br) and K2CO3 in the presence of [Bun4N]Br, followed by acid-catalyzed isomerization with camphorsulfonic acid. These compounds provide access to a new class of alkyl ligands that feature oxygen donors and are capable of forming metallacarbatranes and a monovalent thallium alkyl compound.

Graphical abstract: Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound

Supplementary files

Article information

Article type
Communication
Submitted
07 Aug 2013
Accepted
08 Aug 2013
First published
29 Aug 2013

Dalton Trans., 2013,42, 14053-14057

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound

A. Al-Harbi, Y. Rong and G. Parkin, Dalton Trans., 2013, 42, 14053 DOI: 10.1039/C3DT52163J

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