Issue 25, 2013
From the journal:

Organic & Biomolecular Chemistry

First studies directed towards the diastereoselective synthesis of the BCD tricyclic core of brownin F†

Fabien Rodier,a   Jean-Luc Parrain,a   Gaëlle Chouraqui*a  and  Laurent Commeiras*a  

* Corresponding authors

a Aix Marseille Université, CNRS, iSm2 UMR 7313, 13397 Marseille cedex 20, France
E-mail: gaelle.chouraqui@univ-amu.fr, laurent.commeiras@univ-amu.fr
Fax: (+33)-(0)4 91 28 91 87
Tel: (+33)-(0)4 91 28 91 88

Abstract

The BCD tricyclic core of brownin F was prepared in eight synthetic operations for the first time. Our synthesis features a diastereo-, chemo- and regioselective intramolecular [3 + 2] cycloaddition between a cyclic carbonyl ylide and a γ-alkylidenebutenolide.

Graphical abstract: First studies directed towards the diastereoselective synthesis of the BCD tricyclic core of brownin F

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3OB40363G
Article type
Paper
Submitted
19 Feb 2013
Accepted
24 Apr 2013
First published
24 Apr 2013

Org. Biomol. Chem., 2013,11, 4178-4185

Permissions

Request permissions

First studies directed towards the diastereoselective synthesis of the BCD tricyclic core of brownin F

F. Rodier, J. Parrain, G. Chouraqui and L. Commeiras, Org. Biomol. Chem., 2013, 11, 4178 DOI: 10.1039/C3OB40363G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements