Issue 15, 2015
From the journal:

CrystEngComm

Zero-strain reductive intercalation in a molecular framework†

Joshua A. Hill,a   Andrew B. Cairns, ORCID logo a   Jared J. K. Lim,a   Simon J. Cassidy,a   Simon J. Clarkea  and  Andrew L. Goodwin*a  

* Corresponding authors

a Department of Chemistry, University of Oxford, Inorganic Chemistry Laboratory, South Parks Road, Oxford, OX1 3QR, UK
E-mail: andrew.goodwin@chem.ox.ac.uk
Fax: +44 (0)1865 274690
Tel: +44 (0)1865 272137

Abstract

Reductive intercalation of potassium within the molecular framework Ag3[Fe(CN)6] gives rise to a volume strain that is an order of magnitude smaller than is typical for common ion-storage materials. We suggest that framework flexibility might be exploited as a general strategy for reducing cycling strain in battery and ion-storage materials.

Graphical abstract: Zero-strain reductive intercalation in a molecular framework

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Article information

DOI
https://doi.org/10.1039/C4CE02364A
Article type
Communication
Submitted
29 Nov 2014
Accepted
22 Dec 2014
First published
08 Jan 2015
This article is Open Access
Creative Commons BY license

CrystEngComm, 2015,17, 2925-2928

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Zero-strain reductive intercalation in a molecular framework

J. A. Hill, A. B. Cairns, J. J. K. Lim, S. J. Cassidy, S. J. Clarke and A. L. Goodwin, CrystEngComm, 2015, 17, 2925 DOI: 10.1039/C4CE02364A

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